Bis(tribenzylammonium) tetrachloridoaurate(III) chloride
نویسندگان
چکیده
In the title compound, (C(21)H(22)N)(2)[AuCl(4)]Cl, the Au(III) atom adopts a square-planar coordination geometry defined by four chloride ions. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds link the organic cations and the uncoordinated chloride ion.
منابع مشابه
Bis(2,6-dimethylpyridine-κN)gold(I) tetrachloridoaurate(III)
In the cation of the title compound, [Au(C(7)H(9)N)(2)][AuCl(4)], the Au(I) atom is two-coordinated in a linear arrangement by two N atoms from two 2,6-dimethyl-pyridine ligands. In the anion, the Au(III) atom has a virtually square-planar coordination geometry. The Au atoms both are located on centers of inversion. The crystal structure involves inter-molecular C-H⋯Cl hydrogen bonds.
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Mono and bis hexamethylenetetramine iron(III) chloride, Fe(N C ,H ) CI (I) and Fe(N C ,H ) Cl (II) were synthesized by the reaction of iron(III) chloride and hexamethylenetetramine (HMTA) in chloroform. Chemical analysis and spectral results show the coordination of HMTA to the iron(III). Electronic transition spectra of compound I and I1 were also studied in coordinating and noncoordinatin...
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The Au(III) atom in the title compound, (C(11)H(7)N(2)O)[AuCl(4)]·C(11)H(6)N(2)O, is in a nearly square-planar environment defined by four Cl atoms. The protonated 9-oxo-4,5-diaza-fluoren-4-ium cation forms an N-H⋯N hydrogen bond with the neutral 4,5-diaza-fluoren-9-one mol-ecule.
متن کاملDichlorido(4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)gold(III) tetrachloridoaurate(III)
In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordination. In the crystal structure, intra- and inter-molecular C-H⋯Cl hydrogen bonds are found.
متن کامل6,6′-Dimethyl-2,2′-bipyridin-1-ium tetrachloridoaurate(III)
In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distance = 3.5419 (19) Å] result in the formation of a supra-molecular structure.
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